Molemole Municipality is located within the Capricorn district Municipality which is in the Limpopo province, also located about 60km North of Polokwane. Molemole Municipality's head office is situated in the town of Mogwadi, formerly known as Dendron. The municipality has two satellite offices namely Morebeng office located in Soekmekaar and Moletjie located in Ga - Phaudi.

The Municipality is bordered to the south by Polokwane municipality, to the North West by Blouberg Municipality to the south east by greater letaba municipality and to the north by Makhado Municipality. Molemole forms part of the four municipalities that makes up Capricorn district municipality, namely Blouberg municipality, Lepelle - nkumpi Municipality and Polokwane municipality. One national road, the N1 crosses through the municipal area linking Molemole with Zimbabwe to the north. The Provincial road P94/1 (R521) passes through the municipality and links Molemole to Botswana to the west. Molemole Municipality comprises of the following settlements which are located across all 16 wards.

The First Cluster: Located in the eastern side of the municipality, this cluster includes Morebeng, Capricorn Park, Nthabiseng, Mokomene

The Second Cluster: This cluster represents a linear settlement pattern with largest concentration of settlements and is situated along the N1 road between Polokwane and Makhado. It includes settlements such as Mphakane, Ramatjowe, and Sefene

The Third Cluster: Found in the western section of the municipality, this cluster includes Mogwadi and the rural villages surrounding Mohodi and Maponto. The majority of the population resides in the Mohodi and Maponto communities, while Mogwadi serves as the administrative hub of the municipality.

The Fourth Cluster: This cluster comprises settlements on bought farms and all the villages of Moletji. These villages are scattered and host a relatively low population density